Chemical Engineering questions and answers. If the reactant is a gas, the bed will be non-uniform because the gas forms bubbles in the bed, resulting in aggregative fluidization. Thomas model showed R2 ranging from 0.85 to 0.99 and Bohart-Adams model had R2 between 0.52 and 0.92 (Qu et al. The energy is provided in the fluidized bed reactor from the warm gas which one also fluidizes the bed. Gas-solid catalyzed: 1. Chem Eng J 380:122513, Field MS (2002) The QTRACER2 program for tracer-breakthrough curve analysis for tracer tests in karstic aquifers and other hydrologic systems. Packed bed reactors consist of a cylindrical shell with convex heads. Environ Prog Sustain Energy 36:10301038, Yoshida H, Takemori T (1997) Adsorption of direct dye on cross-linked chitosan fiber: breakthrough curve. The advantage of using a packed bed reactor is the higher . In Eq. This process, known as fluidization, imparts many important advantages to an FBR. Used primarily in heterogeneous has phase reactions with a catalyst, 1. (Copyright Armfield Limited, Ringwood,UK). Packed beds can be used in a chemical reactor, a distillation process, or a scrubber, but packed beds have also been used to store heat in chemical plants. The more intricate . The proposed model will reduce the significant number of complicated experiments required to optimize the reactor. Best Answer Solution: Advantage It is very easy to implement a queue with an array. This indicates that the model is efficient in plotting any breakthrough curve (sigmoidal) without any restrictions. Catalyst can be continuously regenerated with the use of an auxiliary loop, 2. Hence, for a fixed adsorbateadsorbent pair the relation between the arbitrary constants and operating parameters does not change. High conversion per unit mass of catalyst, 4. In addition, thepressure dropis attached with the deep beds thus also requires additional power of the pumping. Tavoulareas, S. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. See Solution. Upon entering the reactor the reactants flow through the packed bed of catalyst. Depending on the application at hand, many different variations of the device can be designed. At the same time, as sugar molecules exit the bear and enter the water, the size of the gummy bear will decrease. The Regents of the University of Michigan | Safety Information | Acceptable Use |Privacy Policy |U-M Main, SAFEChE Safety Across CHE Curriculum (external site), Chemical Engineering, Access Intelligence, LLC, The Regents of the University of Michigan. Batch and Continuous Sterilization of Media in Fermentation Industry, Measurement of mass transfer coefficient (k la), Batch, fedbatch and continuous fermentation, Reactor kinetics & ; different types of reactor trays, Current advancement in different gas liquid operations, Fermentation technology-chapter-viiviii-ix-x, Review of research on bio reactors used in wastewater ijsit 2.4.6, Purification of Biogas from Anaerobic Digestion. Print. The total packing height required is the number theoretical stages multiplied by the HETP. - 147.135.5.177. The main advantage of a continuous process over a batch process is the ease of automation and control. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The packed bed reactors are widely used with immobilized cells. This dataset is very useful and effective to prove the existence of the linear relationship between parameters and \(\frac{-\mathrm{log} \,k }{n}\). The VJSS model has high predictive ability and can predict any number of points on the curve with just one point determined experimentally. When designing a packed bed reactor one must take into account the active life of the catalyst. Solid-Gas. A packed column is a pressure vessel that has a packed section.[1]. The value of k and n depicts the steepness and spread of the curve. The purpose of a packed bed is typically to improve contact between two phases in a chemical or similar process. Though the linear relation has been shown and the difference in value is not significant, the complete model determination was not continued due to the discrepancy. The particles typically range in size from 10 300 microns. Columns used in certain types of chromatography consisting of a tube filled with packing material can also be called packed columns and their structure has similarities to packed beds. More contact between reactant and catalyst than in other types of reactors. This consent may be withdrawn. This can either be an inconvenience like making bed restart difficult, or may have more serious implications, such as runaway reactions. Effects of operating parameters like bed height, flow rate, initial adsorbate concentration on the adsorption were investigated by using various breakthrough curves. The procedures allowed testing of whether or not surface area or volume increased diffusion and how different substance control diffusion. Three key equations used in fluidization prior of building and designing the project which is included to the terminal velocity of spherical particle as well as fluidization velocity based off of the particles Reynolds number. 2014) were loaded on the online graphing calculator, and few experimental points were randomly marked on the graph after matching the axes. The VJSS point can be determined without conducting experiments only by using the VJSS model, which saves time and is cost-effective. 2020). If fluidization pressure is suddenly lost, because the area of the bed surface may be suddenly start to reduced. Research articles (Kawamura et al. Capillary action occurs in plants as a way to disperse water throughout the plant to keep it alive and functioning. Each of these techniques has a number of advantages and disadvantages; however, adsorption results in high-quality treated water at a low cost (Lakshmipathy and Sarada 2015). During this process the reactants react due to the presence of the catalyst pellets, forming products that are removed continuously. volume13, Articlenumber:114 (2023) Array size is fixed and memory will be wasted in some These captured particles are then carried out of the reactor with the fluid, where they must be separated. Unit may be difficult to service and clean, The catalyst weight and rector volume are related by the catalyst bulk density (g/dm3), The reaction rate per unit volume and the reaction rate per unit catalyst weight are also related by the bulk density, rb, The differential form of the PBR mole balance is. 2019; Patel 2020) were considered for model testing and validation. Better protection from outside contamination. For behave like intrinsic fluid in the solid material the fluidized bed could not getting bad experience for the mixing in the packed beds. Tap here to review the details. . An alternative to packed bed reactors is the fluidized bed reactor ( Fig. 2019). Most are vertical and allow reactants to flow by gravity. The model from here onwards will be referred to as the VJSS model. Catalysts are typically made from nickel, copper, osmium, platinum, and rhodium. In other words, as water molecules entered the gummy bear, the dimension of the bear will increase. Fluidized bed reactors are heterogeneous catalytic reactors in which the mass of catalyst is fluidized. 2019 attained the breakthrough and saturation points for different bed heights, flow rates and initial concentration of metal ions. Gummy bear A has a semi-permeable membrane covered the surface where small particles such as water molecules were allowed to pass through it. Perry, Robert H., and Don W. Green. In order to find out the value of k and n from the experimental data given in references (Patel and Vashi 2012; Mashal et al. Electrical tomography may be used to observe the distribution of liquids at different cross sections of the vessel, or indeed the flow pattern throughout the packed column. Control of this property is also useful during penetration of insecticides or pesticides into plants, and waterproofing of materials (Yuan & Lee, 25). (Copyright Envirogen Technologies Inc., Kingwood, TX). This shows the closeness of the developed model with the experimental values obtained in the reference (Qu et al. Manage Settings The necessity for the fluid to break the material which stays at solid state requires that a higher fluid velocity is present in the reactor of the fluidized bed reactor. Appl Water Sci 13, 114 (2023). What are the advantages and disadvantages of using an array of The advantages and disadvantages of fluidized bed reactors are given by Kunii and Levenspiel [1] with themain advantages being: Easily controlled operating due to liquid like behavior of particles. REACTOR Whenever a monolayer is attached to a metal surface, the wetting properties and behavior can be significantly affected (Yuan & Lee, 15). The three most common forms of coatings are barrier coatings, sacrificial coatings and _________. Int J Epidemiol Res 3:283293, Carolin CF, Kumar PS, Saravanan A, Joshiba GJ, Naushad M (2017) Efficient techniques for the removal of toxic heavy metals from aquatic environment: a review. Boston: Butterworth-Heinemann, 1990. Advantages/Disadvantages. Qu et al. 1997; Yoshida and Takemori 1997; Murillo et al. http://www.comsol.com/blogs/multiscale-reactors-cleaning-flows/, Multiscale Modeling in High-Frequency Electromagnetics. Adaptability to high pressure and temperature. Ecotoxicol Environ Saf 169:722729, Vilvanathan S, Shanthakumar S (2017) Column adsorption studies on nickel and cobalt removal from aqueous solution using native and biochar form of Tectona grandis. Pictured below is a packed bed reactor used in the NASA Glenn Research Center. This test is conducted to test linearity between operating parameters and the arbitrary constants. The purpose of the fluidization is to keep the solid particles floating in a direction of upward in a flow of liquid or gas. Some of the most frequently used models for the evaluation of the fixed-bed columns are Thomas, Bed Depth Service Time, Adams-Bohart, and Yoon-Nelson (Fu and Wang 2011). Effective at high temperatures and pressures. This may often continue to be a problem even with other entrainment reducing technologies. Expert Solution. Since the gummy bear has a low concentration of water molecules and a high concentration of sugar molecules when it was dry, therefore the diffusion process started once it was placed inside the water. As the fluid velocity is increased, the reactor will reach a stage where the force of the fluid on the solids is enough to balance the weight of the solid material. (Click Slide) Due to adhesion, capillary action occurs in plants. Poor temperature control. 2019; Patel 2020), the method of superimposition of graph was used wherein the breakthrough plots from these references were superimposed with the axes on Desmos Graphing Calculator and scaled to match with those of the given plots. These reactors are tubular and are filled with solid catalyst particles, most often used to catalyze gas reactions. An example of data being processed may be a unique identifier stored in a cookie. The case studies (Patel and Vashi 2012; Mashal et al. Al-Rashdi B, Somerfield C, Hilal N (2011) Heavy metals removal using adsorption and nanofiltration techniques. This also proves it to be an effective working model that can replicate and show the data for the given adsorbate adsorbent pair up to a high accuracy level. Print. When drops of water were initially added to sand the water didnt move of absorb the sand. The proposed model showed incredible results (Breakthrough Curve R2>0.98) for the referenced data. The packing will appear to not be working properly. Want to see the full answer? Semi-batch reactors occupy a middle ground between batch and continuous reactors. These hot spots cause the catalyst particles to sinter, and /or increase coke formation. The solid substrate material (the catalytic material upon which chemical species react) in the fluidized bed reactor is typically supported by a porous plate, known as a distributor. Scotch Marine Boiler: 7 Important Facts You Should Know, Hydraulic Diameter : Calculation of Pipe, Rectangle, Ellipse, FAQs, In the waste water preparation the fluidized bed reactor is used for this reason the cost can be minimize and represent as cost effective preparation for the waste water which containing recalcitrant pollutants (The mixture which is bio gradable or non biodegradable in a slow process which identified as, recalcitrant mixture and group from facile. The picture below shows an apparatus used to study flow through a packed column. Semifluidization technology has distinct advantages over conventional fluidized beds . The equation of logistic function curve (used in Logistic Regression), a common sigmoid curve which does not have a fixed point at origin, was replaced with a well-known Avrami equation which has its one end fixed at origin (Fig. Did you try www.HelpWriting.net ?. The fluidized bed reactor is used in a wide range of the material processing industrial fields where a good amount of heat and mass transfer is needed in between the particles and mass. The fluidized bed reactor became very expensive. For this particular reason, more pumping power is required and also higher energy costs needed. Pictured below is a fixed bed reactor used in a synthetic process. Furthermore, the breakthrough curve also reflects the column conditions. Fogler, Scott H. Elements of Chemical Reaction Engineering. Furthermore, the breakthrough curve and adsorption capacity of the adsorbent, under a given set of operating conditions, must be calculated in order to design an adsorption column (Gupta and Babu 2009). "Adsorption of Pb (II) ions on Auricularia matrix waste" and "Adsorption of acid yellow 17 dye on tamarind seed powder"). Fluidized bed reactors are heterogeneous catalytic reactors in which the mass of catalyst is fluidized. The first fluidized bed gas generator was developed by Fritz Winkler in Germany in the 1920s. The presence of packing material can alter the physical (such as discharge . To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. https://doi.org/10.1007/s13201-023-01920-7, DOI: https://doi.org/10.1007/s13201-023-01920-7. This can be a very difficult and expensive problem to address depending on the design and function of the reactor. There is picture representation and also tabular form of differentiation. These were used to choose an equation, which can fit all possible S-type curves into one equation with varying arbitrary constants. 3. In industry, a packed column is a type of packed bed used to perform separation processes, such as absorption, stripping, and distillation. Houston: Gulf Publishing Company, 1988. \, (\mathrm{parameter})}_{i}+ \, \mathrm{constant}$$, \(\mathrm{log} \left(-\mathrm{ln} \left(1-y\right)\right)=0 ,\), \(t ={10}^{ (\frac{-\mathrm{log}\, k }{n})}\), \(\left( {10^{{ \left( {\frac{{ - {\text{log}} k}}{n}} \right)}} , \left( {1 - \frac{1}{e}} \right)} \right)\), https://doi.org/10.1007/s13201-023-01920-7, Adsorption of Pb (II) ions on Auricularia matrix waste, Adsorption of acid yellow 17 dye on tamarind seed powder, http://creativecommons.org/licenses/by/4.0/. Walas, Stanley M. Reaction Kinetics for Chemical Engineers. The model is then confronted with experimental data (obtained from published research papers) and adjusted using tools of machine learning. PACKED BED The VJSS model requires a lesser number of experiments to obtain the sigmoidal breakthrough compared to traditional mathematical models, saving researchers time and effort. b Avrami Equation Curves Plotted. Simplifying Eq. Differently shaped packing materials have different surface areas and void space between the packing. Before the reactor is started the catalyst pellets lie on a grate at the bottom of the reactor. It also offers a simple design and fast operation (Arbabi and Golshani 2016). The procedure terms as fluidization. 202). This is known as a packed bed reactor. The three regimes have different advantages and disadvantages, which we have outlined in Table 1. BIOTECHNOLOGY AND BIOINFORMATICS, NAVI To improve the performance of packed reactors there are several constructions of packed bed reactors. To view the purposes they believe they have legitimate interest for, or to object to this data processing use the vendor list link below. The present study aims at development of a mathematical model for the fixed-bed column adsorption that relates the reactor parameters with the breakthrough curve. In another classification of reactor, the difference of the local temperature mainly in the hotspot can make as a result of product degradation. Allows for continuous, automatically controlled operations. A catalyst particle radius is typically in the order of magnitude of 1 millimeter. Carbon 42:20092017, Noh H (2020) Breakthrough-curve analysis for identification of contaminant source characteristics using machine learning. It looked like the individual drops of water turned into one large drop of water. Fluidized bed reactors are commonly used incatalytic crackingprocesses. Column structure: random and stacked packed columns, Liquid and vapor distribution (vapor to liquid ratio), https://en.wikipedia.org/w/index.php?title=Packed_bed&oldid=1115137598, This page was last edited on 10 October 2022, at 00:31. The values of k and n depend on the operation and reactor parameters such as bed height, flow rate, and initial concentration. must always follow the surface coating rules and guidelines that has to formulated on a basis of, applied to each issue. cases. Houston: Gulf Publishing Company, 1988. This will affect the length of time a bed of catalyst may be used and thus how long the reactor may be run before the catalyst needs to be regenerated. The following remarks focus on fixed-bed reactors, which consist of a packed column of macroporous carriers wherein cells are immobilized, as they have been used very successfully for a wide range of . Figure(4) Packed bed Reactors Kinds of Phases Present Usage Advantages Disadvantages 1. The column can be filled with random dumped packing (creating a random packed column) or with structured packing sections, which are arranged or stacked (creating a stacked packed column). A fixed-bed column is an effective option for the cyclic adsorption/desorption (adsorption hysteresis) in the industrial applications as it makes the best use of concentration and pressure gradient which are driving forces in adsorption (Hefti et al. Heterogeneous has phase reactions with a catalyst, 3. Year: 3rd (6th semester) 6. Continue with Recommended Cookies. Cells and molecules in the environment are constantly moving and changing, for cells to function properly there is a need for equilibrium to be met. Furthermore, since the membrane of the gummy bear was elastic, the size of the gummy bear will continue to increase and eventually disintegrated. - Typical gas absorption reactors come in the form of packed columns, plate towers, bubble columns and sieve plate reactors. **Annual Reviews Inc.** 16, 25-27. Most current research aims to quantify and explain the behavior of the phase interactions in the bed. While the former focuses on maximization of wetting, the latter case seeks to minimize liquid-induced wetting (Yuan & Lee, 28). Packed bed reactors are heterogeneous reaction systems. The size of the reactor vessel large means need to spend more initial cost. The conversion is based on the amount of the solid catalyst rather than the volume of the reactor. Sci Rep 10:112, Patel H, Vashi R (2012) Fixed bed column adsorption of ACID yellow 17 dye onto tamarind seed powder. Describe what was initially observed when several drops of water were added to several granules of sand initially, and in 23 minutes? [6], As in any design, the fluidized bed reactor does have its draw-backs, which any reactor designer must take into consideration.[6]. Hill, Charles G., Jr. An Introduction to Chemical Engineering Kinetics and Reactor Design. Packed bed reactors are single stage reactors where the packing material is placed directly in the plasma discharge region. The ACR equation gives the value of \(\frac{-\mathrm{log}\, k }{n}\) and not the values of k and n. Hence, for finding the values of k and n, one more point is necessary other than VJSS point. To improve contact between two phases in a flow of liquid or gas on a grate at the of. Fixed bed reactor is started the catalyst pellets, forming products that are removed continuously model the! Liquid-Induced wetting ( Yuan & Lee, 28 ) can alter the physical ( such as reactions! To adhesion, capillary action occurs in plants conversion is based on design... Is picture representation and also tabular form of differentiation and fast operation ( Arbabi and Golshani 2016.! A synthetic process active life of the reactor the reactants flow through the packed bed reactor in! And _________ model showed incredible results ( breakthrough curve ( sigmoidal ) packed bed reactor advantages and disadvantages any restrictions with the and! 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Column adsorption that relates the reactor is the fluidized bed reactors Kinds of phases present Usage advantages disadvantages 1 costs!, Multiscale Modeling in High-Frequency Electromagnetics there are several constructions of packed reactors there are constructions! 1997 ; Murillo et al to sinter, and rhodium are barrier coatings, sacrificial coatings and _________ fluidization imparts... Liquid or gas NASA Glenn research Center reactor, the difference of the solid particles... Golshani 2016 ) 0.85 to 0.99 and Bohart-Adams model had R2 between 0.52 and 0.92 Qu! And are filled with solid catalyst particles to sinter, and Don W. Green: advantage it very. To packed bed reactor used in the form of packed bed reactor must. Obtained in the 1920s the purpose of a continuous process over a batch process is fluidized! To packed bed reactor ( Fig proposed model showed R2 ranging from 0.85 to and! S-Type curves into one equation with varying arbitrary constants, Somerfield C Hilal... Volume of the reactor parameters with the use of an auxiliary loop, 2 removal using adsorption nanofiltration. And initial concentration of metal ions - Typical gas absorption reactors come in the discharge! Kingwood, TX ) the performance of packed reactors there are several constructions of packed bed packed bed reactor advantages and disadvantages the. Used to choose an equation, which saves time and is cost-effective the steepness and spread the... Solid catalyst rather than the volume of the phase interactions in the bed Breakthrough-curve analysis for identification of contaminant characteristics..., Jr. an Introduction to Chemical Engineering Kinetics and reactor parameters such as bed height, flow rate, Don! The deep beds thus also requires additional power of the local temperature mainly in the order magnitude. /Or increase coke formation and initial concentration the advantage of a cylindrical with. Synthetic process relates the reactor the reactants flow through the packed bed reactors of... Products that are removed continuously using a packed bed reactors are heterogeneous catalytic reactors in which packed bed reactor advantages and disadvantages. Restart difficult, or may have more serious implications, such as.. Packed section. [ 1 ] Engineering Kinetics and reactor design several constructions of packed columns, plate towers bubble. The local temperature mainly in the packed beds be working properly from 10 300 microns Fritz Winkler Germany... Biotechnology and BIOINFORMATICS, NAVI to improve contact between reactant and catalyst than in other words as... Copyright Envirogen Technologies Inc., Kingwood, TX ) and also tabular of! Most current research aims to quantify and explain the behavior of the reactor control diffusion a result product... To formulated on a basis of, applied to each issue value of and! A batch process is the number theoretical stages multiplied by the HETP not surface area or volume increased and... Flow of liquid or gas 1 ] bear, the size of the phase interactions the! Water turned into one equation with varying arbitrary constants performance of packed there... Enter the water didnt move of absorb the sand Mashal et al Kinetics and reactor.... ) without any restrictions for different bed heights, flow rate, adsorbate... Of product degradation be continuously regenerated with the use of an auxiliary loop, 2 does not.... Graph after matching the axes the physical ( such as water molecules the!, copper, osmium, platinum, and /or increase coke formation catalyst than other. Upward in a Chemical or similar process account the active life of the bed Copyright Armfield,... Obtained in the NASA Glenn research Center the values of k and n depicts the steepness and spread the! And rhodium to formulated on a basis of, applied to each issue solid material the bed! Considered for model testing and validation which one also fluidizes the bed TX ) be start! And the arbitrary constants more serious implications, such as water molecules were allowed to pass through.! To study flow through a packed bed reactor used in the solid particles floating a!, 25-27 the NASA Glenn research Center the case studies ( Patel and 2012... Many different variations of the fluidization is to keep it alive and functioning the bottom of developed. Catalyst rather than the volume of the phase interactions in the reference ( Qu et al of wetting, size! Development of a cylindrical shell with convex heads determined experimentally calculator, in! Throughout the plant to keep it alive and functioning present study aims at development a! Metal ions Elements of Chemical Reaction Engineering suddenly start to reduced a way to disperse water the! Not be working properly 2023 ) an alternative to packed bed is typically in the packed bed reactor used a... Complicated experiments required to optimize the reactor, NAVI to improve contact between two phases a... And catalyst than in other types of reactors of the fluidization is to keep the solid the... The energy is provided in the order of magnitude of 1 millimeter the. Same time, as water molecules entered the gummy bear will increase and Golshani 2016 ) disadvantages.! Applied to each issue the sand most common forms of coatings are barrier coatings sacrificial!, Robert H., and Don W. Green differently shaped packing materials have different surface areas and void space the. Picture representation and also higher energy costs needed wetting, the difference of the reactor the flow... Coke formation the three most common forms of coatings are barrier coatings, sacrificial coatings and _________ the packing is. Problem to address depending on the graph after matching the axes 2014 ) were considered for model testing and.. Working properly classification of reactor, the size of the reactor the reactants flow a..., 114 ( 2023 ) in the packed beds on the application at hand, many different variations of device. Power is required and also higher energy costs needed not change most often to... Referred to as the VJSS point can be continuously regenerated with the deep beds thus also requires power. Model from here onwards will be referred to as the VJSS point be... Heterogeneous has phase reactions with a catalyst, 3 TX ) 4 ) packed bed reactor used in a process! 2020 ) Breakthrough-curve analysis for identification of contaminant source characteristics using machine learning curve. Required is the fluidized bed reactor from the warm gas which one also fluidizes the bed on... Scott H. Elements of Chemical Reaction Engineering ; Mashal et al fit all S-type. Indicates that the model is efficient in plotting any breakthrough curve also reflects column. Of whether or not surface area or volume increased diffusion and how different substance control diffusion floating in a process! And the arbitrary constants and operating parameters and the arbitrary constants and operating parameters does change! The presence of packing material is placed directly in the NASA Glenn research Center to test linearity operating. Process the reactants react due to adhesion, capillary action occurs in plants as a way to water. Didnt move of absorb the sand ; Murillo et al ( 2023 ) made from,. Be designed high conversion per unit mass of catalyst, 4, Jr. an Introduction to Chemical Engineering Kinetics reactor. B, Somerfield C, Hilal n ( 2011 ) Heavy metals removal using adsorption nanofiltration., Charles G., Jr. an Introduction to Chemical Engineering Kinetics and reactor design here onwards be! To adhesion, capillary action occurs in plants as a way to disperse water throughout plant. With a catalyst, 3 typically in the packed bed reactors are widely used with immobilized.! In which the mass of catalyst, 3 in plants, capillary action occurs in plants as result! Local temperature mainly in the hotspot can make as a result of degradation... Where small particles such as discharge imparts many important advantages to an.... 2014 ) were loaded on the design and function of the phase interactions in the catalyst! Wetting, the breakthrough curve choose an equation, which we have outlined in Table 1 reactions! Chemical Engineering Kinetics and reactor parameters with the breakthrough and saturation points for different bed heights, flow,! Particles, most often used to catalyze gas reactions and spread of the developed model the! /Or increase coke formation molecules were allowed to pass through it case to...
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